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Sodium thiosulfate (sodium thiosulphate) is an inorganic compound with the formula Na 2 S 2 O 3 ·(H 2 O) x. Typically it is available as the white or colorless pentahydrate (x = 5), which is a white solid that dissolves well in water. The compound is a reducing agent and a ligand, and these properties underpin its applications. [2]
12.69 is the conversion factor from mEq sodium thiosulfate to grams of iodine (the molecular weight of iodine is 126.9 g/mol); W is the weight of the sample in grams. The determination of IV according to Wijs is the official method currently accepted by international standards such as DIN 53241-1:1995-05, AOCS Method Cd 1-25, EN 14111 and ISO ...
The triiodide ion solution is then titrated against standard thiosulfate solution to give iodide again using starch indicator: I − 3 + 2 e − ⇌ 3 I − (E 0 = +0.54 V) Together with reduction potential of thiosulfate: [1] S 4 O 2− 6 + 2 e − ⇌ 2 S 2 O 2− 3 (E 0 = +0.08 V) The overall reaction is thus: I − 3 + 2 S 2 O 2− 3 → S ...
Sodium thiocyanate (sometimes called sodium sulphocyanide) is the chemical compound with the formula NaSCN. This colorless deliquescent salt is one of the main sources of the thiocyanate anion . As such, it is used as a precursor for the synthesis of pharmaceuticals and other specialty chemicals . [ 2 ]
Ammonium thiosulfate (ammonium thiosulphate in British English) is an inorganic compound with the formula [NH 4] 2 S 2 O 3. It is white crystalline solid with ammonia odor, readily soluble in water , slightly soluble in acetone and insoluble in ethanol and diethyl ether .
Sodium sulfate is a typical electrostatically bonded ionic sulfate. The existence of free sulfate ions in solution is indicated by the easy formation of insoluble sulfates when these solutions are treated with Ba 2+ or Pb 2+ salts: Na 2 SO 4 + BaCl 2 → 2 NaCl + BaSO 4. Sodium sulfate is unreactive toward most oxidizing or reducing agents.
The ammonium, sodium, and potassium salts adopt very similar structures in the solid state, according to X-ray crystallography. In the ammonium salt, the O-O distance is 1.497 Å. The sulfate groups are tetrahedral , with three short S-O distances near 1.44 Å and one long S-O bond at 1.64 Å.
The sample solution is then distilled with a small amount of sodium hydroxide (NaOH). [3] NaOH can also be added with a dropping funnel. [4] NaOH reacts the ammonium (NH 4 +) to ammonia (NH 3), which boils off the sample solution. Ammonia bubbles through the standard acid solution and reacts back to ammonium salts with the weak or strong acid. [3]