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Cementite (or iron carbide) is a compound of iron and carbon, more precisely an intermediate transition metal carbide with the formula Fe 3 C. By weight, it is 6.67% carbon and 93.3% iron. It has an orthorhombic crystal structure. [4]
iron: ferrite, ferritic steel; iron: austenite, austenitic steel; iron carbide: cementite, Fe3C. It shows a eutectic and a eutectoid; these phases crystallise as a stacking of fine strips of pure phases (iron and cementite) in case of the eutectoid, or a pure iron containing small balls of cementite for the eutectic.
Iron-cementite meta-stable diagram. Cast iron's properties are changed by adding various alloying elements, or alloyants. Next to carbon, silicon is the most important alloyant because it forces carbon out of solution. A low percentage of silicon allows carbon to remain in solution, forming iron carbide and producing white cast iron.
Low-pressure phase diagram of pure iron. BCC is body centered cubic and FCC is face-centered cubic. Iron-carbon eutectic phase diagram, showing various forms of Fe x C y substances. Iron allotropes, showing the differences in structure. The alpha iron (α-Fe) is a body-centered cubic (BCC) and the gamma iron (γ-Fe) is a face-centered cubic (FCC).
English: Iron-carbon binary phase diagram: metastable (cementite) in plain line; stable (graphite) in dashed line. Caption: Fe 3 C: cementite (iron carbide); L: liquid; α: ferrite (alpha iron), body-centered cubic; δ: delta-iron, body-centered cubic; γ: austenite (gamma iron), face-centered cubic; solvus A 1: lower limit of existence of ...
Martensite is formed in carbon steels by the rapid cooling of the austenite form of iron at such a high rate that carbon atoms do not have time to diffuse out of the crystal structure in large enough quantities to form cementite (Fe 3 C). Austenite is gamma-phase iron (γ-Fe), a solid solution of iron and alloying elements.
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
Iron-carbon phase diagram, showing the conditions under which austenite (γ) is stable in carbon steel. Allotropes of iron; alpha iron and gamma iron. Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron with an alloying element. [1]