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In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. [1] Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter.
Myoglobin sketch Alpha helix. 1958 – Myoglobin was the very first crystal structure of a protein molecule. [2] Myoglobin cradles an iron-containing heme group that reversibly binds oxygen for use in powering muscle fibers, and those first crystals were of myoglobin from the sperm whale, whose muscles need copious oxygen storage for deep dives.
Stacking faults occur in a number of crystal structures, but the common example is in close-packed structures. They are formed by a local deviation of the stacking sequence of layers in a crystal. An example would be the ABABCABAB stacking sequence. A twin boundary is a defect that introduces a plane of mirror symmetry in the ordering of a crystal.
The fcc structure is a close-packed structure unlike the bcc structure; thus the volume of the iron decreases when this transformation occurs. Crystallography is useful in phase identification. When manufacturing or using a material, it is generally desirable to know what compounds and what phases are present in the material, as their ...
Another common type of crystallographic defect is an impurity, meaning that the "wrong" type of atom is present in a crystal. For example, a perfect crystal of diamond would only contain carbon atoms, but a real crystal might perhaps contain a few boron atoms as well. These boron impurities change the diamond's color to slightly blue.
The structure can also be described as an FCC lattice of zinc with sulfur atoms occupying half of the tetrahedral voids or vice versa. [6] Examples of compounds with this structure include zincblende itself, lead(II) nitrate, many compound semiconductors (such as gallium arsenide and cadmium telluride), and a wide array of other binary compounds.
Monoclinic crystal An example of the monoclinic crystal orthoclase. In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram ...
Of the three common crystalline structures bcc, fcc, and hcp, the hcp structure is the most likely to form deformation twins when strained, because they rarely have a sufficient number of slip systems for an arbitrary shape change.