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The nitric acid process produces nitric acid for use in making ammonium nitrate fertiliser. Using the Ostwald process, ammonia is vaporised and then oxidised over a 95% platinum and 5% rhodium catalyst at 930 °C (1,710 °F) and 6.5 bar (650 kPa) to form nitric oxide and superheated steam. The reaction gases are cooled to 38 °C (100 °F ...
Ammonium nitrate is an important fertilizer with NPK rating 34-0-0 (34% nitrogen). [17] It is less concentrated than urea (46-0-0), giving ammonium nitrate a slight transportation disadvantage. Ammonium nitrate's advantage over urea is that it is more stable and does not rapidly lose nitrogen to the atmosphere.
As of 2018, the Haber process produces 230 million tonnes of anhydrous ammonia per year. [69] The ammonia is used mainly as a nitrogen fertilizer as ammonia itself, in the form of ammonium nitrate, and as urea. The Haber process consumes 3–5% of the world's natural gas production (around 1–2% of the world's energy supply).
The Haber process, [5] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [ 6 ] [ 7 ] It converts atmospheric nitrogen (N 2 ) to ammonia (NH 3 ) by a reaction with hydrogen (H 2 ) using finely divided iron metal as a catalyst:
The history of the Haber process begins with the invention of the Haber process at the dawn of the twentieth century. The process allows the economical fixation of atmospheric dinitrogen in the form of ammonia, which in turn allows for the industrial synthesis of various explosives and nitrogen fertilizers, and is probably the most important industrial process developed during the twentieth ...
Urea plant using ammonium carbamate briquettes, Fixed Nitrogen Research Laboratory, ca. 1930 Carl Bosch, 1927. The Bosch–Meiser process is an industrial process, which was patented in 1922 [1] and named after its discoverers, the German chemists Carl Bosch and Wilhelm Meiser [2] for the large-scale manufacturing of urea, a valuable nitrogenous chemical.
The Ostwald process begins with burning ammonia.Ammonia burns in oxygen at temperature about 900 °C (1,650 °F) and pressure up to 8 standard atmospheres (810 kPa) [4] in the presence of a catalyst such as platinum gauze, alloyed with 10% rhodium to increase its strength and nitric oxide yield, platinum metal on fused silica wool, copper or nickel to form nitric oxide (nitrogen(II) oxide) and ...
However, ammonium can also be oxidised to nitrate (via nitrite), by the process of nitrification. This is performed by different bacteria in two stages : NH 3 + O 2 → NO 2 − + 3H + + 2e −. NO 2 − + H 2 O → NO 3 − + 2H + + 2e −. Crucially, this process is believed to only occur in the absence of light (or as some other function of ...