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This could ease the theoretical phase diagram generation of multicomponent systems. For alloys containing transition metal elements there is a difficulty in interpretation of the Hume-Rothery electron concentration rule, as the values of e/a values (number of itinerant electrons per atom) for transition metals have been quite controversial for ...
A binary phase diagram displaying solid solutions over the full range of relative concentrations. On a phase diagram a solid solution is represented by an area, often labeled with the structure type, which covers the compositional and temperature/pressure ranges. Where the end members are not isostructural there are likely to be two solid ...
The solidus is the locus of temperatures (a curve on a phase diagram) below which a given substance is completely solid (crystallized). The solidus temperature specifies the temperature below which a material is completely solid, [2] and the minimum temperature at which a melt can co-exist with crystals in thermodynamic equilibrium.
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.
The solvus or solubility line (or curve) is the line (or lines) on a phase diagram that give the limits of solute addition. That is, the lines show the maximum amount of a component that can be added to another component and still be in solid solution .
The underlying reason is that for an eutectic system like Cu-Ag, the solubility in liquid phase is good but solubility in solid phase is limited. Therefore when a silver-copper alloy is frozen, it actually separates into crystals of 912 fineness silver and 80 fineness silver - both are saturated and always have the same composition at the ...
A Lippmann diagram is a graphical plot showing the solidus/solutus equilibrium states for a given binary solid solution (e.g., (Ba 1-x Sr x)SO 4, barite/celestite) in equilibrium with an aqueous solution containing the two substituting ions: Ba 2+ and Sr 2+ (solid solution – aqueous solution system, or SS-AS).
Aluminum-silicon phase diagram. Aluminum forms a eutectic with silicon, which is at 577 °C, with a Si content of 12.5% [7] or 12.6%. [8] Up to 1.65% Si can be dissolved in aluminum at this temperature. However, the solubility decreases rapidly with temperature. At 500 °C it is still 0.8% Si, at 400 °C 0.3% Si and at 250 °C only 0.05% Si.