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Zeolite exhibited in the Estonian Museum of Natural History. Zeolite is a family of several microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. [1] They mainly consist of silicon, aluminium, oxygen, and have the general formula M n+ 1/n (AlO 2) − (SiO 2) x ･y H 2 O where M n+ 1/n is ...
Faujasite (FAU-type zeolite) is a mineral group in the zeolite family of silicate minerals.The group consists of faujasite-Na, faujasite-Mg and faujasite-Ca. They all share the same basic formula (Na 2,Ca,Mg) 3.5 [Al 7 Si 17 O 48]·32(H 2 O) by varying the amounts of sodium, magnesium and calcium. [1]
These materials embody the molecular sieve effect, the preferential sieving of molecules larger than the pores. [a] Many kinds of materials exhibit some molecular sieves, but zeolites dominate the field. Zeolites are almost always aluminosilicates, or variants where some or all of the Si or Al centers are replaced by similarly charged elements. [2]
The typical chemical formula of the unit cell can be described as Q x Na y Al 2.4 Si 33.6 O 72 •zH 2 O (1.4 < x <27)(0.7 < y < 4.3)(1 < z <7), where Q is N,N,N-1-trimethyladamantammonium. [1] The material was patented by Chevron research Company in 1985, [ 3 ] and could potentially be used as a solid catalyst for the methanol -to- olefins ...
Clinoptilolite is a natural zeolite composed of a microporous arrangement of silica and alumina tetrahedra. It has the complex formula (Na,K,Ca) 2–3 Al 3 (Al,Si) 2 Si 13 O 36 •12H 2 O. It forms as white, green to reddish tabular monoclinic tectosilicate crystals with a Mohs hardness of 3.5 to 4 and a specific gravity of 2.1 to 2.2.
Pentasil-zeolites are defined by their structure type, and more specifically by their X-ray diffraction patterns. ZSM -5 is the trade name of a pentasil-zeolite. As early as 1967, Argauer and Landolt worked out parameters for the synthesis of pentasilzeolites, particularly those relating to the following molar ratios: OH − /SiO 2 = 0.07–10, SiO 2 /Al 2 O 3 = 5–100, H 2 O/SiO 2 = 1–240. [1]
Its chemical formula is NaAlSi 2 O 6 · H 2 O. Minor amounts of potassium and calcium substitute for sodium. A silver-bearing synthetic variety also exists (Ag-analcite). Analcime is usually classified as a zeolite mineral, but structurally and chemically it is more similar to the feldspathoids. [1]
Isomorphous with heulandite is the strontium and barium zeolite brewsterite. The Mohs hardness is 3–4, and the specific gravity 2.2. Heulandite is similar to stilbite. The two minerals may, however, be readily distinguished by the fact that in heulandite the acute positive bisectrix of the optic axes emerges perpendicular to the cleavage. [6]