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In order to repeat the reaction, the electron in the reaction center needs to be replenished. This occurs by oxidation of water in the case of oxygenic photosynthesis. The electron-deficient reaction center of photosystem II (P680*) is the strongest biological oxidizing agent yet discovered, which allows it to break apart molecules as stable as ...
Photochemical immersion well reactor (50 mL) with a mercury-vapor lamp.. Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible (400–750 nm), or infrared radiation (750–2500 nm).
The energy of these rays is sometimes sufficient to start photonuclear reactions resulting in emitted neutrons. One such reaction, 14 7 N (γ,n) 13 7 N, is the only natural process other than those induced by cosmic rays in which 13 7 N is produced on Earth. The unstable isotopes remaining from the reaction may subsequently emit positrons by β ...
In one mechanism of the oxidative reaction, holes react with the moisture present on the surface and produce a hydroxyl radical. The reaction starts by photo-induced exciton generation in the metal oxide (MO) surface by photon (hv) absorption: MO + hν → MO (h + + e −) Oxidative reactions due to photocatalytic effect: h + + H 2 O → H ...
Photo-oxidation is a form of photodegradation and begins with formation of free radicals on the polymer chain, which then react with oxygen in chain reactions. For many polymers the general autoxidation mechanism is a reasonable approximation of the underlying chemistry.
Synthetic photoinitiators are key components in photopolymers (for example, photo-curable coatings, adhesives and dental restoratives). Some small molecules in the atmosphere can also act as photoinitiators by decomposing to give free radicals (in photochemical smog).
An example of a synthetically useful Norrish type II reaction can be found early in the total synthesis of the biologically active cardenolide ouabagenin by Phil Baran and coworkers. [15] The optimized conditions minimize side reactions, such as the competing Norrish type I pathway, and furnish the desired intermediate in good yield on a multi ...
Two further early examples were the rearrangement of 1,1,5,5-tetraphenyl-3,3-dimethyl-1,4-pentadiene (the "Mariano" molecule) [22] and the rearrangement of barrelene to semibullvalene. [23] We note that, in contrast to the cyclohexadienone reactions which used n-π * excited states, the di-π-methane rearrangements utilize π-π * excited states.