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Phosphorus triiodide is commonly used in the laboratory for the conversion of primary or secondary alcohols to alkyl iodides. [4] The alcohol is frequently used as the solvent, on top of being the reactant.
The main use for phosphorus tribromide is for conversion of primary or secondary alcohols to alkyl bromides, [9] as described above.PBr 3 usually gives higher yields than hydrobromic acid, and it avoids problems of carbocation rearrangement- for example even neopentyl bromide can be made from the alcohol in 60% yield.
Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula P O Cl 3.It hydrolyses in moist air releasing phosphoric acid and fumes of hydrogen chloride.
Wiley-Interscience, 6th edition, 2007, ISBN 978-0-471-72091-1 Description: A comprehensive reference for organic chemistry with over 25,000 references. Importance: A reference publication.
McMurry's most popular textbook Organic Chemistry was first printed in 1984. In 2022, he sold the rights for the book to OpenStax making it free for the user. [3] [4] Among his other texts are: Organic Chemistry with Biological Applications (3rd edition) [5] Chemistry (8th edition) [6] General Chemistry, Atoms First (2nd edition) [7]
The reduction of nitro compounds are chemical reactions of wide interest in organic chemistry. The conversion can be effected by many reagents. The nitro group was one of the first functional groups to be reduced. Alkyl and aryl nitro compounds behave differently.