Search results
Results From The WOW.Com Content Network
In theoretical chemistry, Specific ion Interaction Theory (SIT theory) is a theory used to estimate single-ion activity coefficients in electrolyte solutions at relatively high concentrations. [ 1 ] [ 2 ] It does so by taking into consideration interaction coefficients between the various ions present in solution.
The Ostwald law of dilution provides a satisfactory description of the concentration dependence of the conductivity of weak electrolytes like CH 3 COOH and NH 4 OH. [3] [4] The variation of molar conductivity is essentially due to the incomplete dissociation of weak electrolytes into ions.
Going towards high dilutions good results have been found using liquid membrane cells, it has been possible to investigate aqueous media 10 −4 M and it has been found that for 1:1 electrolytes (as NaCl or KCl) the Debye–Hückel equation is totally correct, but for 2:2 or 3:2 electrolytes it is possible to find negative deviation from the ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Electrolyte monitoring is important in the treatment of anorexia and bulimia. In science, electrolytes are one of the main components of electrochemical cells. [2] In clinical medicine, mentions of electrolytes usually refer metonymically to the ions, and (especially) to their concentrations (in blood, serum, urine, or other fluids). Thus ...
m is known as the limiting molar conductivity, K is an empirical constant, and c is the electrolyte concentration. ("Limiting" here means "at the limit of the infinite dilution".) In effect, the observed conductivity of a strong electrolyte becomes directly proportional to concentration at sufficiently low concentrations, i.e. when
A supporting electrolyte, in electrochemistry, according to an IUPAC definition, [1] is an electrolyte containing chemical species that are not electroactive (within the range of potentials used) and which has an ionic strength and conductivity much larger than those due to the electroactive species added to the electrolyte.
Hume-Rothery rules, named after William Hume-Rothery, are a set of basic rules that describe the conditions under which an element could dissolve in a metal, forming a solid solution. There are two sets of rules; one refers to substitutional solid solutions, and the other refers to interstitial solid solutions.