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9-Anthracenemethanol is the derivative of anthracene with a hydroxymethyl group (CH 2 OH) attached to the 9-position. It is a colorless solid that is soluble in ordinary organic solvents. The compound can be prepared by hydrogenation of 9-anthracenecarboxaldehyde. It is a versatile precursor to supramolecular assemblies. [1]
Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C 14 H 10, consisting of three fused benzene rings. It is a component of coal tar.Anthracene is used in the production of the red dye alizarin and other dyes, as a Scintillator to detect high energy particles, as production of pharmaceutical drugs.
Anthracene-9-carbaldehyde is the most common monoaldehyde derivative of anthracene. It is a yellow solid that is soluble in common organic solvents. It is prepared by Vilsmeier formylation of anthracene. [1] [2] The compound is also used as a building block for supramolecular assemblies. [3]
The synthesis highlights the ability for functional group tolerance metathesis reactions as well as the ability to access complex molecules of varying ring sizes. [ 56 ] In 2003, Danishefsky and others reported the total synthesis of (+)-migrastatin , a macrolide isolated from Streptomyces which inhibited tumor cell migration. [ 57 ]
2-Methylanthracene-9,10-dione. ... Synthesis and reactions ... The compound is produced by a double electrophilic aromatic substitution reaction of toluene with ...
Figure 6:Reaction Coordinate Diagrams showing reactions with 0, 1 and 2 intermediates: The double-headed arrow shows the first, second and third step in each reaction coordinate diagram. In all three of these reactions the first step is the slow step because the activation energy from the reactants to the transition state is the highest.
If SVG files are required, it is recommended that structure diagrams be exported as enhanced metafiles (.emf) which can be read by Inkscape and other image editors. From the "Options" menu, choose "Set Structure Drawing Style" → ACS Style; Draw the structure or reaction diagram; Export the file as PNG or EMF for further processing (see below)
A fluorous technology was described by Curran [16] The fluorous synthesis employs functionalized perfluoroalkyl (Rf) groups like 4,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluorononyl {CF 3 (CF 2) 4 CF 2 CH 2 CH 2-} group attached to substrates or reagents. The Rf groups make it possible to remove either the product or the reagents from the reaction mixture.