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Cyanide is quantified by potentiometric titration, a method widely used in gold mining. It can also be determined by titration with silver ion. Some analyses begin with an air-purge of an acidified boiling solution, sweeping the vapors into a basic absorber solution. The cyanide salt absorbed in the basic solution is then analyzed. [47]
Hydrogen cyanide (formerly known as prussic acid) is a chemical compound with the formula HCN and structural formula H−C≡N. It is a highly toxic and flammable liquid that boils slightly above room temperature , at 25.6 °C (78.1 °F).
Potassium cyanide is a compound with the formula KCN. It is a colorless salt, similar in appearance to sugar , that is highly soluble in water. Most KCN is used in gold mining , organic synthesis , and electroplating .
Sodium cyanide is a compound with the formula Na C N and the structure Na + − C≡N. It is a white, water-soluble solid. Cyanide has a high affinity for metals, which leads to the high toxicity of this salt .
Calcium cyanide is the inorganic compound with the formula Ca(CN) 2. It is the calcium salt derived from hydrocyanic acid. It is a white solid, although the pure material is rarely encountered. It slowly hydrolyses in solution or moist air to release hydrogen cyanide and is very toxic. [3]
The cyanate ion is an anion with the chemical formula OCN −. It is a resonance of three forms: [O − −C≡N] (61%) ↔ [O=C=N − ] (30%) ↔ [O + ≡C−N 2− ] (4%). Cyanate is the derived anion of isocyanic acid , H−N=C=O, and its lesser tautomer cyanic acid (a.k.a. cyanol), H−O−C≡N.
Zinc cyanide is the inorganic compound with the formula Zn 2. It is a white solid that is used mainly for electroplating zinc but also has more specialized applications for the synthesis of organic compounds .
Mercury(II) cyanide, also known as mercuric cyanide, is a poisonous compound of mercury and cyanide. It is an odorless, toxic white powder. It is highly soluble in polar solvents such as water , alcohol , and ammonia , slightly soluble in ether , and insoluble in benzene and other hydrophobic solvents .