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Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
The energy released when an electron is added to a neutral gaseous atom to form an anion is known as electron affinity. [14] Trend-wise, as one progresses from left to right across a period , the electron affinity will increase as the nuclear charge increases and the atomic size decreases resulting in a more potent force of attraction of the ...
Chemically, the nonmetals mostly have higher ionisation energies, higher electron affinities (nitrogen and the noble gases have negative electron affinities) and higher electronegativity values [n 1] than metals noting that, in general, the higher an element's ionisation energy, electron affinity, and electronegativity, the more nonmetallic ...
The electron affinity is 0.080 eV, which is very close to zero. [2] The helium atom is small with the radius of the outer electron shell at 0.29 Å. [2] Helium is a very hard atom with a Pearson hardness of 12.3 eV. [3] It has the lowest polarizability of any kind of atom, however, very weak van der Waals forces exist between helium and other ...
The electron affinity (usually given by the symbol in solid state physics) gives the energy difference between the lower edge of the conduction band and the vacuum level of the semiconductor. The band gap (usually given the symbol E g {\displaystyle E_{\rm {g}}} ) gives the energy difference between the lower edge of the conduction band and the ...
Therefore, there is an electron chemical potential that might vary in space, causing diffusion. At very high temperatures, however, electrons and positrons can spontaneously appear out of the vacuum ( pair production ), so the chemical potential of electrons by themselves becomes a less useful quantity than the chemical potential of the ...
Binding affinity, a measure of the interaction of ligands with their binding sites; Chemical affinity, used to describe or characterise elements' or compounds' readiness to form bonds; Electron affinity, energy released on formation of anions; Processor affinity, a computing term for the assignment of a task to a given core of a multicore CPU