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However, oxy-fuel is a viable alternative to removing CO 2 from the flue gas from a conventional air-fired fossil fuel plant. However, an oxygen concentrator might be able to help, as it simply removes nitrogen. In industries other than power generation, oxy-fuel combustion can be competitive due to higher sensible heat availability. Oxy-fuel ...
As can be seen in the following reaction, 1,2-dichloroethane is cracked: ClCH 2 CH 2 Cl → CH 2 =CHCl + HCl. The HCl from this cracking process is recycled by oxychlorination in order to reduce the consumption of raw material HCl (or Cl 2, if direct chlorination of ethylene is chosen as main way to produce 1,2-dichloroethane). [3]
Cl 2 + H 2 → 2 HCl. As the reaction is exothermic, the installation is called an HCl oven or HCl burner. The resulting hydrogen chloride gas is absorbed in deionized water, resulting in chemically pure hydrochloric acid. This reaction can give a very pure product, e.g. for use in the food industry. The reaction can also be triggered by blue ...
In the combustion reaction, oxygen reacts with the fuel, and the point where exactly all oxygen is consumed and all fuel burned is defined as the stoichiometric point. With more oxygen (overstoichiometric combustion), some of it stays unreacted. Likewise, if the combustion is incomplete due to lack of sufficient oxygen, fuel remains unreacted.
The system can be flushed with an inert gas to reduce the concentration of oxygen so that when the flammable gas is admitted, an ignitable mixture cannot form. In NFPA 56, [1] this is known as purge-into-service. In combustion engineering terms, the admission of inert gas dilutes the oxygen below the limiting oxygen concentration.
Catalytic oxidation are processes that rely on catalysts to introduce oxygen into organic and inorganic compounds. Many applications, including the focus of this article, involve oxidation by oxygen. Such processes are conducted on a large scale for the remediation of pollutants, production of valuable chemicals, and the production of energy. [1]
A variant of CLC is Chemical-Looping Combustion with Oxygen Uncoupling (CLOU) where an oxygen carrier is used that releases gas-phase oxygen in the fuel reactor, e.g. CuO/ Cu 2 O. [21] This is helpful for achieving high gas conversion, and especially when using solid fuels, where slow steam gasification of char can be avoided.
Consider the first triangular diagram below, which shows all possible mixtures of methane, oxygen and nitrogen. Air is a mixture of about 21 volume percent oxygen, and 79 volume percent inerts (nitrogen). Any mixture of methane and air will therefore lie on the straight line between pure methane and pure air – this is shown as the blue air-line.