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As can be seen in the following reaction, 1,2-dichloroethane is cracked: ClCH 2 CH 2 Cl → CH 2 =CHCl + HCl. The HCl from this cracking process is recycled by oxychlorination in order to reduce the consumption of raw material HCl (or Cl 2, if direct chlorination of ethylene is chosen as main way to produce 1,2-dichloroethane). [3]
The process involves intermediate formation of sodium bisulfate, an exothermic reaction that occurs at room temperature: NaCl + H 2 SO 4 → HCl + NaHSO 4. The second step of the process is endothermic, requiring energy input: NaCl + NaHSO 4 → HCl + Na 2 SO 4. Temperatures in the range 600-700 °C are required. [5]
Cl 2 + H 2 → 2 HCl. As the reaction is exothermic, the installation is called an HCl oven or HCl burner. The resulting hydrogen chloride gas is absorbed in deionized water, resulting in chemically pure hydrochloric acid. This reaction can give a very pure product, e.g. for use in the food industry. The reaction can also be triggered by blue ...
Chlorine can be manufactured by the electrolysis of a sodium chloride solution (), which is known as the Chloralkali process.The production of chlorine results in the co-products caustic soda (sodium hydroxide, NaOH) and hydrogen gas (H 2).
Catalytic oxidation are processes that rely on catalysts to introduce oxygen into organic and inorganic compounds. Many applications, including the focus of this article, involve oxidation by oxygen. Such processes are conducted on a large scale for the remediation of pollutants, production of valuable chemicals, and the production of energy. [1]
The ion-permeable ion-exchange membrane at the center of the cell allows only the sodium ions (Na +) to pass to the second chamber where they react with the hydroxide ions to produce caustic soda (NaOH) (B in figure): [1] Na + + OH − → NaOH The overall reaction for the electrolysis of brine is thus: 2NaCl + 2 H 2 O → Cl 2 + H 2 + 2NaOH
The process was based on the oxidation of hydrogen chloride: 4 HCl + O 2 → 2 Cl 2 + 2H 2 O. The reaction takes place at about 400 to 450 °C in the presence of a variety of catalysts, including copper chloride (CuCl 2).
A chlorate candle, or an oxygen candle, is a cylindrical chemical oxygen generator that contains a mix of sodium chlorate and iron powder, which when ignited smolders at about 600 °C (1,100 °F), producing sodium chloride, iron oxide, and oxygen at a fixed rate of about 6.5 man-hours per kilogram of the mixture. The mixture has an indefinite ...