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Magnified crystals of iron(II,III) oxide (Fe 3 O 4), the end-product of the Schikorr reaction along with hydrogen gas. The Schikorr reaction formally describes the conversion of the iron(II) hydroxide (Fe(OH) 2) into iron(II,III) oxide (Fe 3 O 4). This transformation reaction was first studied by Gerhard Schikorr. The global reaction follows:
Iron(II,III) oxide, or black iron oxide, is the chemical compound with formula Fe 3 O 4. It occurs in nature as the mineral magnetite . It is one of a number of iron oxides , the others being iron(II) oxide (FeO), which is rare, and iron(III) oxide (Fe 2 O 3 ) which also occurs naturally as the mineral hematite .
A thermite mixture using iron(III) oxide. Thermite (/ ˈ θ ɜːr m aɪ t /) [1] is a pyrotechnic composition of metal powder and metal oxide. When ignited by heat or chemical reaction, thermite undergoes an exothermic reduction-oxidation (redox) reaction. Most varieties are not explosive, but can create brief bursts of heat and high ...
Simplified diagram of the iron oxide cycle. For chemical reactions, the iron oxide cycle (Fe 3 O 4 /FeO) is the original two-step thermochemical cycle proposed for use for hydrogen production. [1] It is based on the reduction and subsequent oxidation of iron ions, particularly the reduction and oxidation between Fe 3+ and Fe 2+.
Iron(III) oxide-hydroxide or ferric oxyhydroxide [2] is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH). The compound is often encountered as one of its hydrates, FeO(OH) ·n H 2 O [rust]. The monohydrate FeO(OH) · H 2 O is often referred to as iron(III) hydroxide Fe(OH) 3, [3] hydrated iron oxide, yellow iron oxide ...
The free radicals generated by this process engage in secondary reactions. For example, the hydroxyl is a powerful, non-selective oxidant. [6] Oxidation of an organic compound by Fenton's reagent is rapid and exothermic and results in the oxidation of contaminants to primarily carbon dioxide and water.
In the steam-iron process the iron oxidizes and has to be replaced with fresh metal, in the Lane hydrogen producer the iron is reduced with water gas back to its metallic condition, after which the process restarts. The chemical reactions are [3] 3Fe+ 4H 2 O → Fe 3 O 4 + 4H 2 Fe 3 O 4 + 4CO → 3Fe + 4CO 2. The net chemical reaction is: CO ...
In chemistry, thermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components. [1] The term cycle is used because aside of water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled.