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Given any three values and the fourth can be calculated. Its important to note that the fourth reaction in the series is an inverted homolytic bond cleavage stated in terms of free energy. The chemical transformation for the associated -ΔG˚ is the same it would be for a bond dissociation energy (BDE). However, the -ΔG˚ is not a BDE, since ...
The z-value is a measure of the change of the D-value with varying temperature, and is a simplified version of an Arrhenius equation and it is equivalent to z=2.303 RT T ref /E. [2] The z-value of an organism in a particular medium is the temperature change required for the D-value to change by a factor of ten, or put another way, the ...
The Gran plot is based on the Nernst equation which can be written as E = E 0 + s log { H + } {\displaystyle E=E^{0}+s\log\{H^{+}\}} where E is a measured electrode potential, E 0 is a standard electrode potential, s is the slope, ideally equal to RT/nF, and {H + } is the activity of the hydrogen ion.
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
N i is the number of particles (or number of moles) composing the ith chemical component. This is one form of the Gibbs fundamental equation. [10] In the infinitesimal expression, the term involving the chemical potential accounts for changes in Gibbs free energy resulting from an influx or outflux of particles.
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Ligand efficiency is a measurement of the binding energy per atom of a ligand to its binding partner, such as a receptor or enzyme. [1]Ligand efficiency is used in drug discovery research programs to assist in narrowing focus to lead compounds with optimal combinations of physicochemical properties and pharmacological properties.