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Selenium forms two oxides: selenium dioxide (SeO 2) and selenium trioxide (SeO 3). Selenium dioxide is formed by the reaction of elemental selenium with oxygen: [5] + It is a polymeric solid that forms monomeric SeO 2 molecules in the gas phase. It dissolves in water to form selenous acid, H 2 SeO 3.
A neutralization reaction is a type of double replacement reaction. A neutralization reaction occurs when an acid reacts with an equal amount of a base. This reaction usually produces a salt. One example, hydrochloric acid reacts with disodium iron tetracarbonyl to produce the iron dihydride: 2 HCl + Na 2 Fe(CO) 4 → 2 NaCl + H 2 Fe(CO) 4
Oxidations involving selenium dioxide are often carried out with catalytic amounts of the selenium compound and in presence of a sacrificial catalyst or co-oxidant such as hydrogen peroxide. SeO 2 -based oxidations sometimes afford carbonyl compounds such as ketones , [ 22 ] β- Pinene [ 23 ] and cyclohexanone oxidation to 1,2-cyclohexanedione ...
The original synthesis involved the redistribution reaction of selenium dioxide and selenium tetrachloride. Pure selenium oxydichloride autoionizes to a dimer: [4] SeOCl 2 ↔ (SeO) 2 Cl + 3 + Cl −. The SeOCl 2 is generally a labile Lewis acid and solutions of sulfur trioxide in SeOCl 2 likely form [SeOCl] + [SO 3 Cl] − the same way. [5]
Selenium dioxide is the chemical compound with the formula SeO 2. This colorless solid is one of the most frequently encountered compounds of selenium . It is used in making specialized glasses as well as a reagent in organic chemistry.
Selenium is found in metal sulfide ores, where it substitutes for sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores. Minerals that are pure selenide or selenate compounds are rare. The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells.
Selenium monochloride or diselenium dichloride is an inorganic compound with the formula Se 2 Cl 2. Although a common name for the compound is selenium monochloride, reflecting its empirical formula , IUPAC does not recommend that name, instead preferring the more descriptive diselenium dichloride.
At higher pH, selenide forms. Solutions of hydrogen selenide and selenide are oxidized by air to give elemental selenium: 2 SeH − + O 2 → 2 Se + 2 OH −. Most elements form selenides. They sometimes have salt-like properties, e.g. sodium selenide, but most exhibit covalent bonding, e.g. molybdenum diselenide. Their properties are diverse ...