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  2. Thomas–Fermi model - Wikipedia

    en.wikipedia.org/wiki/Thomas–Fermi_model

    It has, however, found modern applications in many fields through the ability to extract qualitative trends analytically and with the ease at which the model can be solved. The kinetic energy expression of Thomas–Fermi theory is also used as a component in more sophisticated density approximation to the kinetic energy within modern orbital ...

  3. Density functional theory - Wikipedia

    en.wikipedia.org/wiki/Density_functional_theory

    Density functional theory (DFT) is a computational quantum mechanical modelling method used in physics, chemistry and materials science to investigate the electronic structure (or nuclear structure) (principally the ground state) of many-body systems, in particular atoms, molecules, and the condensed phases.

  4. Wannier function - Wikipedia

    en.wikipedia.org/wiki/Wannier_function

    Wannier functions have recently found application in describing the polarization in crystals, for example, ferroelectrics. The modern theory of polarization is pioneered by Raffaele Resta and David Vanderbilt. See for example, Berghold, [9] and Nakhmanson, [10] and a power-point introduction by Vanderbilt. [11]

  5. Molecular mechanics - Wikipedia

    en.wikipedia.org/wiki/Molecular_mechanics

    The Born–Oppenheimer approximation is assumed valid and the potential energy of all systems is calculated as a function of the nuclear coordinates using force fields. Molecular mechanics can be used to study molecule systems ranging in size and complexity from small to large biological systems or material assemblies with many thousands to ...

  6. Function of several real variables - Wikipedia

    en.wikipedia.org/wiki/Function_of_several_real...

    The image of a function f(x 1, x 2, …, x n) is the set of all values of f when the n-tuple (x 1, x 2, …, x n) runs in the whole domain of f.For a continuous (see below for a definition) real-valued function which has a connected domain, the image is either an interval or a single value.

  7. Functional analysis - Wikipedia

    en.wikipedia.org/wiki/Functional_analysis

    The historical roots of functional analysis lie in the study of spaces of functions and the formulation of properties of transformations of functions such as the Fourier transform as transformations defining, for example, continuous or unitary operators between function spaces.

  8. Metadynamics - Wikipedia

    en.wikipedia.org/wiki/Metadynamics

    Metadynamics (MTD; also abbreviated as METAD or MetaD) is a computer simulation method in computational physics, chemistry and biology.It is used to estimate the free energy and other state functions of a system, where ergodicity is hindered by the form of the system's energy landscape.

  9. Ab initio quantum chemistry methods - Wikipedia

    en.wikipedia.org/wiki/Ab_initio_quantum...

    Example Is the bonding situation in disilyne Si 2 H 2 the same as in acetylene (C 2 H 2)? A series of ab initio studies of Si 2 H 2 is an example of how ab initio computational chemistry can predict new structures that are subsequently confirmed by experiment. They go back over 20 years, and most of the main conclusions were reached by 1995.