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Lithium reacts with water easily, but with noticeably less vigor than other alkali metals. The reaction forms hydrogen gas and lithium hydroxide. [10] When placed over a flame, lithium compounds give off a striking crimson color, but when the metal burns strongly, the flame becomes a brilliant silver.
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
The metal reacts with the water first, breaking the hydrogen bonds in the water and producing hydrogen gas; this takes place faster for the more reactive heavier alkali metals. Second, the heat generated by the first part of the reaction often ignites the hydrogen gas, causing it to burn explosively into the surrounding air.
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While classified as a strong base, lithium hydroxide is the weakest known alkali metal hydroxide.
The noble gases do not react with water, but their solubility in water increases when going down the group. Argon atoms in water appear to have a first hydration shell composed of 16±2 water molecules at a distance of 280–540 pm, and a weaker second hydration shell is found out to 800 pm. Similar hydration spheres have been found for krypton ...
All oxides of group 1 & 2 elements are basic (except BeO), they react with water to form a base: [2] Lithium oxide reacts with water to produce lithium hydroxide: Li 2 O + H 2 O → 2 LiOH; Sodium oxide reacts with water to produce sodium hydroxide: Na 2 O + H 2 O → 2 NaOH; Potassium oxide reacts with water to produce potassium hydroxide: K 2 ...
Lithium nitride is prepared by direct reaction of elemental lithium with nitrogen gas: [2] 6 Li + N 2 → 2 Li 3 N. Instead of burning lithium metal in an atmosphere of nitrogen, a solution of lithium in liquid sodium metal can be treated with N 2. Lithium nitride must be protected from moisture as it reacts violently with water to produce ammonia:
Other method for production of Li 2 C 2 is heating of metallic lithium in atmosphere of ethylene. Lithium hydride is a coproduction: 6 Li + C 2 H 4 → Li 2 C 2 + 4 LiH. Lithium carbide hydrolyzes readily to form acetylene as well as Lithium hydroxide: Li 2 C 2 + 2 H 2 O → 2 LiOH + C 2 H 2. Lithium hydride reacts with graphite at 400°C ...