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In surface science, a double layer (DL, also called an electrical double layer, EDL) is a structure that appears on the surface of an object when it is exposed to a fluid. The object might be a solid particle, a gas bubble, a liquid droplet, or a porous body. The DL refers to two parallel layers of charge surrounding the object.
Double layer forces occur between charged objects across liquids, typically water. This force acts over distances that are comparable to the Debye length, which is on the order of one to a few tenths of nanometers. The strength of these forces increases with the magnitude of the surface charge density (or the electrical surface potential). For ...
The double-layer charge forms a static electric field in the molecular IHP layer of the solvent molecules that corresponds to the strength of the applied voltage. The "thickness" of a charged layer in the metallic electrode, i.e., the average extension perpendicular to the surface, is about 0.1 nm, and mainly depends on the electron density ...
The total electrical double layer due to the formation of the counterion layers results in electrostatic screening of the wall charge and minimizes the Gibbs free energy of EDL formation. The thickness of the diffuse electric double layer is known as the Debye screening length /. At a distance of two Debye screening lengths the electrical ...
Electroosmotic flow is caused by the Coulomb force induced by an electric field on net mobile electric charge in a solution. Because the chemical equilibrium between a solid surface and an electrolyte solution typically leads to the interface acquiring a net fixed electrical charge, a layer of mobile ions, known as an electrical double layer or Debye layer, forms in the region near the interface.
The model of the "thin double layer" offers tremendous simplifications not only for electrophoresis theory but for many other electrokinetic and electroacoustic theories. This model is valid for most aqueous systems because the Debye length is typically only a few nanometers in water.
Thermodynamic heat pump cycles or refrigeration cycles are the conceptual and mathematical models for heat pump, air conditioning and refrigeration systems. [1] A heat pump is a mechanical system that transmits heat from one location (the "source") at a certain temperature to another location (the "sink" or "heat sink") at a higher temperature. [2]
A representative pressure–volume diagram for a refrigeration cycle. Vapour-compression refrigeration or vapor-compression refrigeration system (VCRS), [1] in which the refrigerant undergoes phase changes, is one of the many refrigeration cycles and is the most widely used method for air conditioning of buildings and automobiles.