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The energy of an electron is determined by its orbit around the atom, The n = 0 orbit, commonly referred to as the ground state, has the lowest energy of all states in the system. In atomic physics and chemistry , an atomic electron transition (also called an atomic transition, quantum jump, or quantum leap) is an electron changing from one ...
If it is at a higher energy level, it is said to be excited, or any electrons that have higher energy than the ground state are excited. Such a species can be excited to a higher energy level by absorbing a photon whose energy is equal to the energy difference between the levels. Conversely, an excited species can go to a lower energy level by ...
In theoretical chemistry, molecular electronic transitions take place when electrons in a molecule are excited from one energy level to a higher energy level. The energy change associated with this transition provides information on the structure of the molecule and determines many of its properties, such as colour.
Four quantum numbers can describe an electron energy level in a hydrogen-like atom completely: Principal quantum number (n) Azimuthal quantum number (ℓ) Magnetic quantum number (m ℓ) Spin quantum number (m s) These quantum numbers are also used in the classical description of nuclear particle states (e.g. protons and neutrons).
Atoms can be excited by heat, electricity, or light. The hydrogen atom provides a simple example of this concept.. The ground state of the hydrogen atom has the atom's single electron in the lowest possible orbital (that is, the spherically symmetric "1s" wave function, which, so far, has been demonstrated to have the lowest possible quantum numbers).
Electron excitation is the transfer of a bound electron to a more energetic, but still bound state. This can be done by photoexcitation (PE), where the electron absorbs a photon and gains all its energy [1] or by collisional excitation (CE), where the electron receives energy from a collision with another, energetic electron. [2]
The energy change E 2 − E 1 determines the frequency f of the emitted photon. Photons mediate electromagnetic interactions between particles in quantum electrodynamics . An isolated electron at a constant velocity cannot emit or absorb a real photon; doing so would violate conservation of energy and momentum .
The first generally accepted theory of ET was developed by Rudolph A. Marcus (Nobel Prize in Chemistry in 1992) [8] to address outer-sphere electron transfer and was based on a transition-state theory approach. The Marcus theory of electron transfer was then extended to include inner-sphere electron transfer by Noel Hush and Marcus.