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Freezing is a phase transition in which a liquid turns into a solid when its temperature is lowered below its freezing point. [ 1 ] [ 2 ] For most substances, the melting and freezing points are the same temperature; however, certain substances possess differing solid-liquid transition temperatures.
On the other hand, some constants, such as K f (the freezing point depression constant, or cryoscopic constant), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore may be considered physical properties. "Specific" properties are expressed on a per mass basis.
Density (g cm-3) Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1] Lauric ...
Following the 2019 revision of the SI, the value of the triple point of water is no longer used as a defining point. However, its empirical value remains important: the unique combination of pressure and temperature at which liquid water , solid ice , and water vapor coexist in a stable equilibrium is approximately 273.16 ± 0.0001 K [ 4 ] and ...
Examples of other defining points are the triple point of hydrogen (−259.3467 °C) and the freezing point of aluminum (660.323 °C). Thermometers calibrated per ITS–90 use complex mathematical formulas to interpolate between its defined points. ITS–90 specifies rigorous control over variables to ensure reproducibility from lab to lab.
The phenomenon of freezing-point depression has many practical uses. The radiator fluid in an automobile is a mixture of water and ethylene glycol. The freezing-point depression prevents radiators from freezing in winter. Road salting takes advantage of this effect to lower the freezing point of the ice it is placed on.
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Freezing point depression and boiling point elevation In chemistry , colligative properties are those properties of solutions that depend on the ratio of the number of solute particles to the number of solvent particles in a solution, and not on the nature of the chemical species present. [ 1 ]