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Liquefaction of gases is physical conversion of a gas into a liquid state (condensation). The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using, for example, turboexpanders .
Liquid oxygen has a clear cyan color and is strongly paramagnetic: it can be suspended between the poles of a powerful horseshoe magnet. [2] Liquid oxygen has a density of 1.141 kg/L (1.141 g/ml), slightly denser than liquid water, and is cryogenic with a freezing point of 54.36 K (−218.79 °C; −361.82 °F) and a boiling point of 90.19 K (−182.96 °C; −297.33 °F) at 1 bar (14.5 psi).
As an example of the latter, a "major commercial application of liquefaction is the liquefaction of air to allow separation of the constituents, such as oxygen, nitrogen, and the noble gases." [4] Another is the conversion of solid coal into a liquid form usable as a substitute for liquid fuels. [5]
Liquid oxygen is so magnetic that, in laboratory demonstrations, a bridge of liquid oxygen may be supported against its own weight between the poles of a powerful magnet. [37] [c] Singlet oxygen is a name given to several higher-energy species of molecular O 2 in which all the electron spins are paired.
Cailletet succeeded in producing droplets of liquid oxygen [1] in 1877 by a different method than Raoul Pictet: He used the Joule-Thomson effect; oxygen was cooled while highly compressed, then allowed to rapidly expand, cooling it further, resulting in the production of small droplets of liquid oxygen. [2]
A nitrogen generator Bottle of 4Å molecular sieves. Pressure swing adsorption provides separation of oxygen or nitrogen from air without liquefaction. The process operates around ambient temperature; a zeolite (molecular sponge) is exposed to high pressure air, then the air is released and an adsorbed film of the desired gas is released.
Most humans can function at rest with an oxygen level of 15% at one atmosphere pressure; [1] a fuel such as methane is combustable down to 12% oxygen in nitrogen. A small room of 10 meter 3 has 2.08 meter 3 (2080 liters) or 2.99 kg of oxygen which would occupy 2.62 liters if it was liquid. [2]
Linde's 1895 patent.. The Hampson–Linde cycle is a process for the liquefaction of gases, especially for air separation. William Hampson and Carl von Linde independently filed for patents of the cycle in 1895: Hampson on 23 May 1895 and Linde on 5 June 1895.