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Tafel plot for an anodic process . The Tafel equation is an equation in electrochemical kinetics relating the rate of an electrochemical reaction to the overpotential. [1] The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel.
In electrochemistry, exchange current density is a parameter used in the Tafel equation, Butler–Volmer equation and other electrochemical kinetics expressions. The Tafel equation describes the dependence of current for an electrolytic process to overpotential.
The overpotential increases with growing current density (or rate), as described by the Tafel equation. An electrochemical reaction is a combination of two half-cells and multiple elementary steps. Each step is associated with multiple forms of overpotential. The overall overpotential is the summation of many individual losses.
Julius Tafel was born in the village of Choindez in Courrendlin, Switzerland on 2 June 1862. Tafel's father, Julius Tafel Sr. (1827-1893) studied chemistry in Tubingen and became a director of Von Roll’s iron and steel works located in Choindez in 1856, and then took a top management position in steel works located in Gerlafingen in 1863.
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The templates {} and {{EquationRef}} can be used to number equations. The template {{EquationNote}} can be used to refer to a numbered equation from surrounding text. For example, the following syntax: {{NumBlk |: |< math > x ^ 2 + y ^ 2 + z ^ 2 = 1 </ math >|{{EquationRef | 1}}}} produces the following result (note the equation number in the ...
The math template formats mathematical formulas generated using HTML or wiki markup. (It does not accept the AMS-LaTeX markup that <math> does.) The template uses the texhtml class by default for inline text style formulas, which aims to match the size of the serif font with the surrounding sans-serif font (see below).
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