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Rubidium perchlorate can be obtained through the careful heating of a rubidium chlorate solution, leading to a disproportionation reaction with the release of oxygen gas: [3] 2 RbClO 3 → RbClO 4 + RbCl + O 2. When heated, it decomposes into the chloride and oxygen: [4] RbClO 4 → RbCl + 2 O 2. It has two polymorphs.
A perchlorate is a chemical compound containing the perchlorate ion, ClO − 4, the conjugate base of perchloric acid (ionic perchlorate). As counterions, there can be metal cations, quaternary ammonium cations or other ions, for example, nitronium cation (NO + 2). The term perchlorate can also describe perchlorate esters or covalent ...
Magnesium perchlorate is a powerful oxidizing agent, with the formula Mg(ClO 4) 2. The salt is also a superior drying agent for gas analysis. Magnesium perchlorate decomposes at 250 °C. [2] The heat of formation is -568.90 kJ/mol. [3] The enthalpy of solution is quite high, so reactions are done in large amounts of water to dilute it.
Chloride cycle dealkalizers operate similar to sodium cycle cation water softeners. Like water softeners, dealkalizers contain ion-exchange resins that are regenerated with a concentrated salt solution - NaCl. In the case of a water softener, the cation exchange resin is exchanging sodium (the Na + ion of NaCl) for hardness minerals such as ...
From a microbial standpoint, the presence of natural chlorate could also explain why there is a variety of microorganisms capable of reducing chlorate to chloride. Further, the evolution of chlorate reduction may be an ancient phenomenon as all perchlorate reducing bacteria described to date also utilize chlorate as a terminal electron acceptor ...
Sodium perchlorate is the precursor to ammonium, potassium and lithium perchlorate salts, often taking advantage of their low solubility in water relative to NaClO 4 (209 g/(100 mL) at 25 °C). [6] It is used for denaturating proteins in biochemistry and in standard DNA extraction and hybridization reactions in molecular biology.