Search results
Results From The WOW.Com Content Network
The characteristic rotational temperature (θ R or θ rot) is commonly used in statistical thermodynamics to simplify the expression of the rotational partition function and the rotational contribution to molecular thermodynamic properties.
For quasi-static and reversible processes, the first law of thermodynamics is: d U = δ Q − δ W {\displaystyle dU=\delta Q-\delta W} where δQ is the heat supplied to the system and δW is the work done by the system.
Rotational energies are quantized. For a diatomic molecule like CO or HCl, or a linear polyatomic molecule like OCS in its ground vibrational state, the allowed rotational energies in the rigid rotor approximation are = = (+) = (+). J is the quantum number for total rotational angular momentum and takes all integer values starting at zero, i.e., =,,, …, = is the rotational constant, and is ...
The function was first introduced by Wu (1952) and has acquired the widely used name rothalpy. [ 2 ] This quantity is commonly called rothalpy, a compound word combining the terms rotation and enthalpy.
An example is the calculation of the rotational kinetic energy of the Earth. As the Earth has a sidereal rotation period of 23.93 hours, it has an angular velocity of 7.29 × 10 −5 rad·s −1. [2] The Earth has a moment of inertia, I = 8.04 × 10 37 kg·m 2. [3] Therefore, it has a rotational kinetic energy of 2.14 × 10 29 J.
The partition function is a function of the temperature T and the microstate energies E 1, E 2, E 3, etc. The microstate energies are determined by other thermodynamic variables, such as the number of particles and the volume, as well as microscopic quantities like the mass of the constituent particles.
Thermodynamics is expressed by a mathematical framework of thermodynamic equations which relate various thermodynamic quantities and physical properties measured in a laboratory or production process. Thermodynamics is based on a fundamental set of postulates, that became the laws of thermodynamics.
A diatomic gas is axially symmetric about only one axis, so that D = 5, comprising translational motion along three axes and rotational motion along two axes. A polyatomic gas, like water, is not radially symmetric about any axis, resulting in D = 6, comprising 3 translational and 3 rotational degrees of freedom.