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Maxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the thermodynamic potentials. These relations are named for the nineteenth-century physicist James Clerk Maxwell .
The thermodynamic square can also be used to find the first-order derivatives in the common Maxwell relations.The following procedure should be considered: Looking at the four corners of the square and make a shape with the quantities of interest.
Maxwell's equations, or Maxwell–Heaviside equations, are a set of coupled partial differential equations that, together with the Lorentz force law, form the foundation of classical electromagnetism, classical optics, electric and magnetic circuits.
Entropy cannot be measured directly. The change in entropy with respect to pressure at a constant temperature is the same as the negative change in specific volume with respect to temperature at a constant pressure, for a simple compressible system. Maxwell relations in thermodynamics are often used to derive thermodynamic relations. [2]
A thermodynamic potential (or more accurately, a thermodynamic potential energy) [1] [2] is a scalar quantity used to represent the thermodynamic state of a system.Just as in mechanics, where potential energy is defined as capacity to do work, similarly different potentials have different meanings.
In summary, Maxwell's equations successfully unified theories of light and electromagnetism, which is one of the great unifications in physics. [9] Maxwell built a simple flywheel model of electromagnetism, and Boltzmann built an elaborate mechanical model ("Bicykel") based on Maxwell's flywheel model, which he used for lecture demonstrations. [10]
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Thermodynamic diagrams usually show a net of five different lines: isobars = lines of constant pressure; isotherms = lines of constant temperature; dry adiabats = lines of constant potential temperature representing the temperature of a rising parcel of dry air