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Diethyl ether, or simply ether, is an organic compound with the chemical formula (CH 3 CH 2) 2 O, sometimes abbreviated as Et 2 O. [ a ] It is a colourless, highly volatile , sweet-smelling ("ethereal odour"), extremely flammable liquid .
The Williamson ether synthesis is an organic reaction, forming an ether from an organohalide and a deprotonated alcohol . This reaction was developed by Alexander Williamson in 1850. [ 2 ] Typically it involves the reaction of an alkoxide ion with a primary alkyl halide via an S N 2 reaction .
log 10 of Diethyl Ether vapor pressure. Uses formula: log e P m m H g = {\displaystyle \scriptstyle \log _{e}P_{mmHg}=} log e ( 760 101.325 ) − 12.4379 log e ( T + 273.15 ) − 6340.514 T + 273.15 + 95.14704 + 1.412918 × 10 − 05 ( T + 273.15 ) 2 {\displaystyle \scriptstyle \log _{e}({\frac {760}{101.325}})-12.4379\log _{e}(T+ ...
The reaction mechanism of the Mitsunobu reaction is fairly complex. The identity of intermediates and the roles they play has been the subject of debate. Initially, the triphenyl phosphine (2) makes a nucleophilic attack upon diethyl azodicarboxylate (1) producing a betaine intermediate 3, which deprotonates the carboxylic acid (4) to form the ion pair 5.
This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.
In chemistry, a transition metal ether complex is a coordination complex consisting of a transition metal bonded to one or more ether ligand. The inventory of complexes is extensive. [2] Common ether ligands are diethyl ether and tetrahydrofuran. Common chelating ether ligands include the glymes, dimethoxyethane (dme) and diglyme, and the crown ...
Good solvents are likely to be diethyl ether and hexane. (However, PE only dissolves at temperatures well above 100 °C.) (However, PE only dissolves at temperatures well above 100 °C.) Poly(styrene) has a solubility parameter of 9.1 cal 1/2 cm −3/2 , and thus ethyl acetate is likely to be a good solvent.
In moisture-free air, solid sodium ethoxide can form sodium ethyl carbonate from fixation of carbon dioxide from the air. Further reactions lead to degradation into a variety of other sodium salts and diethyl ether. [9] This instability can be prevented by storing sodium ethoxide under an inert atmosphere (e.g., N 2).