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  2. Thermodynamic databases for pure substances - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_databases...

    Row 9. Values of the six parameters for the third H T - H 298 equation; temperature limit for the equation, and ΔH° trans for the third phase change. Row 10. Number of ΔH° form equations required. Here five; three for species phases and two because one of the elements has a phase change. Row 11.

  3. Hess's law - Wikipedia

    en.wikipedia.org/wiki/Hess's_law

    Combination of chemical equations leads to a net or overall equation. If the enthalpy changes are known for all the equations in the sequence, their sum will be the enthalpy change for the net equation. If the net enthalpy change is negative (<), the reaction is exothermic and is more likely to be spontaneous; positive ΔH values correspond to ...

  4. Phase transition - Wikipedia

    en.wikipedia.org/wiki/Phase_transition

    In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter : solid , liquid , and gas , and in rare cases, plasma .

  5. Stefan problem - Wikipedia

    en.wikipedia.org/wiki/Stefan_problem

    This is accomplished by solving heat equations in both regions, subject to given boundary and initial conditions. At the interface between the phases (in the classical problem) the temperature is set to the phase change temperature. To close the mathematical system a further equation, the Stefan condition, is required. This is an energy balance ...

  6. Thermochemical equation - Wikipedia

    en.wikipedia.org/wiki/Thermochemical_equation

    In thermochemistry, a thermochemical equation is a balanced chemical equation that represents the energy changes from a system to its surroundings. One such equation involves the enthalpy change, which is denoted with Δ H {\displaystyle \Delta H} In variable form, a thermochemical equation would appear similar to the following:

  7. Thermochemistry - Wikipedia

    en.wikipedia.org/wiki/Thermochemistry

    Thermochemistry is the study of the heat energy which is associated with chemical reactions and/or phase changes such as melting and boiling. A reaction may release or absorb energy, and a phase change may do the same. Thermochemistry focuses on the energy exchange between a system and its surroundings in the form of heat. Thermochemistry is ...

  8. Chemical thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Chemical_thermodynamics

    Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...

  9. Cooling curve - Wikipedia

    en.wikipedia.org/wiki/Cooling_curve

    When the phase change occurs, there is a "thermal arrest"; that is, the temperature stays constant. This is because the matter has more internal energy as a liquid or gas than in the state that it is cooling to. The amount of energy required for a phase change is known as latent heat. The "cooling rate" is the slope of the cooling curve at any ...