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Acetonitrile, often abbreviated MeCN (methyl cyanide), is the chemical compound with the formula CH 3 CN and structure H 3 C−C≡N. This colourless liquid is the simplest organic nitrile (hydrogen cyanide is a simpler nitrile, but the cyanide anion is not classed as organic). It is produced mainly as a byproduct of acrylonitrile manufacture.
[Cu(MeCN) 4] +, often encountered as its PF 6 − salt, is a common transition metal nitrile complex. Transition metal nitrile complexes are coordination compounds containing nitrile ligands. Because nitriles are weakly basic, the nitrile ligands in these complexes are often labile .
The cation was first reported in 1923 with a nitrate anion as a byproduct of the reduction of silver nitrate with a suspension of copper powder in acetonitrile. [4] [ Cu(CH 3 CN) 4]PF 6 is generally produced by the addition of HPF 6 to a suspension of copper(I) oxide in acetonitrile: [5]
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Solvent Density (g cm-3) Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1 ...
Pages in category "Non-petroleum based lubricants" The following 13 pages are in this category, out of 13 total. This list may not reflect recent changes. B.