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An amorphous silicon (a-Si) solar cell is made of non-crystalline or microcrystalline silicon. Amorphous silicon has a higher bandgap (1.7 eV) than crystalline silicon (c-Si) (1.1 eV), which means it absorbs the visible part of the solar spectrum more strongly than the higher power density infrared portion of the spectrum.
First generation solar cells are made of crystalline silicon, also called, conventional, traditional, wafer-based solar cells and include monocrystalline (mono-Si) and polycrystalline (multi-Si) semiconducting materials. Second generation solar cells or panels are based on thin-film technology and are of commercially significant importance.
Polycrystalline silicon is the key feedstock in the crystalline silicon based photovoltaic industry and used for the production of conventional solar cells. For the first time, in 2006, over half of the world's supply of polysilicon was being used by PV manufacturers. [ 6 ]
Amorphous silicon (a-Si) is the non-crystalline form of silicon used for solar cells and thin-film transistors in LCDs. Used as semiconductor material for a-Si solar cells , or thin-film silicon solar cells , it is deposited in thin films onto a variety of flexible substrates, such as glass, metal and plastic.
Solar cell efficiencies vary from 6% for amorphous silicon-based solar cells to 44.0% with multiple-junction production cells and 44.4% with multiple dies assembled into a hybrid package. [23] [24] Solar cell energy conversion efficiencies for commercially available multicrystalline Si solar cells are around 14–19%. [25]
For most crystalline silicon solar cells the change in V OC with temperature is about −0.50%/°C, though the rate for the highest-efficiency crystalline silicon cells is around −0.35%/°C. By way of comparison, the rate for amorphous silicon solar cells is −0.20 to −0.30%/°C, depending on how the cell is made.
The J-V characteristics (J is current density, i.e. current per unit area) of a solar cell under illumination are obtained by shifting the J-V characteristics of a diode in the dark downward by I ph. Since solar cells are designed to supply power and not absorb it, the power P = VI ph must be negative.
As the foundation for silicon-based discrete components and integrated circuits, it plays a vital role in virtually all modern electronic equipment, from computers to smartphones. Additionally, mono-Si serves as a highly efficient light-absorbing material for the production of solar cells, making it indispensable in the renewable energy sector.