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Circular dichroism (CD) is the differential absorption of left- and right-handed circularly polarized light. Circular dichroism is the basis of a form of spectroscopy that can be used to determine the optical isomerism and secondary structure of molecules. In general, this phenomenon will be exhibited in absorption bands of any optically active ...
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity.
A change in Kerr rotation is most easily recognized in linearly polarized light, which can be separated into two circularly polarized components: Left-handed circular polarized (LHCP) light and right-handed circular polarized (RHCP) light. The anisotropy of the magneto-optic material permittivity causes a difference in the speed of LHCP and ...
Circular dichroism causes incident linearly polarized light to become elliptically polarized. The two phenomena are closely related, just as are ordinary absorption and dispersion. If the entire optical rotatory dispersion spectrum is known, the circular dichroism spectrum can be calculated, and vice versa.
In this case, the Pockels cell is acting as a quarter wave plate, where linearly-polarized light is converted to circularly-polarized light. With the addition of a Brewster window (left), this change in polarization can be converted to a change in the intensity of the beam, by transmitting only the p-polarized vector component.
Polarized light with its electric field along the plane of incidence is thus denoted p-polarized, while light whose electric field is normal to the plane of incidence is called s-polarized. P -polarization is commonly referred to as transverse-magnetic (TM), and has also been termed pi-polarized or π -polarized , or tangential plane polarized .
Circular dichroism (CD) is dichroism involving circularly polarized light, i.e., the differential absorption of left- and right-handed light. [1] [2] Left-hand circular (LHC) and right-hand circular (RHC) polarized light represent two possible spin angular momentum states for a photon, and so circular dichroism is also referred to as dichroism for spin angular momentum. [3]
Linearly polarized white light which passes through the plate becomes elliptically polarized, except for that green light wavelength, which will remain linear. If a linear polarizer oriented perpendicular to the original polarization is added, this green wavelength is fully extinguished but elements of the other colors remain.