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This is sometimes called the reverse water–gas shift reaction. [20] Water gas is defined as a fuel gas consisting mainly of carbon monoxide (CO) and hydrogen (H 2). The term 'shift' in water–gas shift means changing the water gas composition (CO:H 2) ratio. The ratio can be increased by adding CO 2 or reduced by adding steam to the reactor.
The water gas shift reaction is the reaction between carbon monoxide and steam to form hydrogen and carbon dioxide: CO + H 2 O ⇌ CO 2 + H 2. This reaction was discovered by Felice Fontana and nowadays is adopted in a wide range of industrial applications, such as in the production process of ammonia, hydrocarbons, methanol, hydrogen and other chemicals.
Water-gas-shift reaction. The reaction that occurs in a water-gas-shift reactor is CO + H 2 O CO 2 + H 2. This produces a syngas with a higher composition of hydrogen fuel which is more efficient for burning later in combustion. Physical separation process.
Natural gas has a high hydrogen to carbon ratio, so the water-gas shift is not needed for cobalt catalysts. Cobalt-based catalysts are more sensitive than their iron counterparts. Illustrative of real world catalyst selection, high-temperature Fischer–Tropsch (HTFT), which operates at 330–350 °C, uses an iron-based catalyst.
Water gas is a kind of fuel gas, a mixture of carbon monoxide and hydrogen. It is produced by "alternately hot blowing a fuel layer [coke] with air and gasifying it with steam". It is produced by "alternately hot blowing a fuel layer [coke] with air and gasifying it with steam".
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This gas is composed almost entirely of CO and H 2, and burns with a pale blue flame similar to natural gas. BWG has a calorific value of 11 MJ/m 3 (300 BTU/cu ft). Blue water gas lacked illuminants; it would not burn with a luminous flame in a simple fishtail gas jet as existed prior to the invention of the gas mantle in the 1890s. Various ...
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