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The glass–liquid transition, or glass transition, is the gradual and reversible transition in amorphous materials (or in amorphous regions within semicrystalline materials) from a hard and relatively brittle "glassy" state into a viscous or rubbery state as the temperature is increased. [2] An amorphous solid that exhibits a glass transition ...
In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter : solid , liquid , and gas , and in rare cases, plasma .
Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites. [1][2] Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation.
Phase transitions (phase changes) that help describe polymorphism include polymorphic transitions as well as melting and vaporization transitions. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure."
The phase behavior of polymer solutions is an important property involved in the development and design of most polymer-related processes. Partially miscible polymer solutions often exhibit two solubility boundaries, the upper critical solution temperature (UCST) and the LCST, both of which depend on the molar mass and the pressure. At ...
Flory–Fox equation. In polymer chemistry and polymer physics, the Flory–Fox equation is a simple empirical formula that relates molecular weight to the glass transition temperature of a polymer system. The equation was first proposed in 1950 by Paul J. Flory and Thomas G. Fox while at Cornell University. [1]
Amorphous polymers (A) do not exhibit other phase transitions. However, semicrystalline polymers (B) undergo crystallization and melting (at temperatures T c and T m, respectively). DSC is used widely for examining polymeric materials to determine their thermal transitions. Important thermal transitions include the glass transition temperature ...
The onset temperature of the transition zone, moving from glassy to rubbery, is known as the glass transition temperature, or T g. In the 1940s Andrews and Tobolsky [ 6 ] showed that there was a simple relationship between temperature and time for the mechanical response of a polymer.