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It can be prepared by base-catalyzed isomerization of 2,3-dimethyl-1-butene. [2] Another route involves direct dimerization of propylene. [3] It can also be produced by photolysis of tetramethylcyclobutane-1,3-dione. [4]
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
2,3-Dimethyl-1-butene; 3,3-Dimethyl-1-butene; 2,3-Dimethyl-2-butene This page was last edited on 20 October 2020, at 08:55 (UTC). Text is available under the Creative ...
2,3-Dimethyl-1-butene is an organic compound with the formula CH 2 =C(CH 3)CH(CH 3) 2. Like the other isomers of dimethylbutene , it is a colorless liquid. Together with 2,3-dimethyl-2-butene it can be produced by dimerization of propylene .
tert-Butylbenzene is an organic compound classified as an aromatic hydrocarbon. Its structure consists of a benzene ring substituted with a tert -butyl group . It is a flammable colorless liquid which is nearly insoluble in water but miscible with organic solvents.
Pinacolone (3,3-dimethyl-2-butanone) is an important ketone in organic chemistry. It is a colorless liquid with a slight peppermint or camphor odor. It is a precursor to triazolylpinacolone in the synthesis of the fungicide triadimefon and in synthesis of the herbicide metribuzin. The molecule is an unsymmetrical ketone. The α-methyl group can ...
Tetra-tert-butylethylene is a hypothetical organic compound, a hydrocarbon with formula C 18 H 36, or ((H 3 C−) 3 C−) 2 C=C(−C(−CH 3) 3) 2. As the name indicates, its molecular structure can be viewed as an ethylene molecule H 2 C=CH 2 with the four hydrogens replaced by tert -butyl −C(−CH 3 ) 3 groups.
Isobutylene (or 2-methylpropene) is a hydrocarbon with the chemical formula (CH 3) 2 C=CH 2. It is a four-carbon branched alkene (olefin), one of the four isomers of butylene . It is a colorless flammable gas, and is of considerable industrial value.