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A common method for hydroxymethylation involves the reaction of formaldehyde with active C-H and N-H bonds: R 3 C-H + CH 2 O → R 3 C-CH 2 OH R 2 N-H + CH 2 O → R 2 N-CH 2 OH. A typical active C-H bond is provided by a terminal acetylene [1] or the alpha protons of an aldehyde. [2]
Para tertiary butylphenol formaldehyde resin, also known as p-tert-butylphenol-formaldehyde resin (PTBP-FR), is a thermoplastic phenol-formaldehyde resin found in commercial adhesives, particularly glues used to bond leather and rubber. It has broad usage in a large variety of industries and can be found in many household textile products and ...
Phenol-formaldehyde resins, as a group, are formed by a step-growth polymerization reaction that can be either acid- or base-catalysed.Since formaldehyde exists predominantly in solution as a dynamic equilibrium of methylene glycol oligomers, the concentration of the reactive form of formaldehyde depends on temperature and pH.
This makes the hydroxymethyl group an alcohol. It has the identical chemical formula with the methoxy group (−O−CH 3) that differs only in the attachment site and orientation to the rest of the molecule. However, their chemical properties are different. [1] [2] Hydroxymethyl is the side chain of encoded amino acid serine. [3]
[12] [13] From the 1990s onward, concern has been raised over the use of BADGE-based epoxy resins in the lining of some cans for foodstuffs, with the chemical being found to leach into foods. [ 12 ] [ 14 ] Bisphenol A Diglycidyl ether-based epoxy coatings are extensively used for coating the inside of cans which come into contact with food and ...
Phenol-formaldehyde resins (PF) were the first commercially relevant impregnation resins, made by reacting phenol and formaldehyde, creating a polymer network inside of the wood upon curing. [7] Phenol can react with formaldehyde at the ortho and para positions, generating mono, di, and trimethylolphenol as the reaction products. [6]
Bisphenol A is difunctional and used to produce epoxy resin and polycarbonate. 4-tert-Butylphenol is monofunctional and so in polymer science terms, bisphenol A is a polymer chain extender but 4-tert-butylphenol is a chain stopper or sometimes called endcapper. It is thus use to control molecular weight by limiting chain growth.
2,4,6-Tris(dimethylaminomethyl)phenol is an aromatic organic chemical that has tertiary amine and phenolic hydroxyl functionality in the same molecule. [1] The formula is C 15 H 27 N 3 O and the CAS Registry Number is 90-72-2. It is REACH registered and the European Community Number is 202-013-9. [2] [3] [4]