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Likewise, when there is a deficit of carriers (i.e., <), the generation rate becomes greater than the recombination rate, again driving the system back towards equilibrium. [1] As the electron moves from one energy band to another, the energy and momentum that it has lost or gained must go to or come from the other particles involved in the ...
Allylic strain in an olefin. Allylic strain (also known as A 1,3 strain, 1,3-allylic strain, or A-strain) in organic chemistry is a type of strain energy resulting from the interaction between a substituent on one end of an olefin (a synonym for an alkene) with an allylic substituent on the other end. [1]
Click chemistry is an approach to chemical ... Diels-alder reaction to release furan and give 1,2,3- or 1,4,5-triazoles. ... useful in a new generation of ...
Diradicals are usually triplets.The phrases singlet and triplet are derived from the multiplicity of states of diradicals in electron spin resonance: a singlet diradical has one state (S=0, M s =2*0+1=1, m s =0) and exhibits no signal in EPR and a triplet diradical has 3 states (S=1, M s =2*1+1=3, m s =-1; 0; 1) and shows in EPR 2 peaks (if no hyperfine splitting).
Crystal structure of a first-generation polyphenylene dendrimer reported by Müllen et al [5] A first-generation "cyanostar" dendrimer and its STM image [6]. The first dendrimers were made by divergent synthesis approaches by Fritz Vögtle in 1978, [7] R.G. Denkewalter at Allied Corporation in 1981, [8] [9] Donald Tomalia at Dow Chemical in 1983 [10] and in 1985, [11] [12] and by George R ...
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
Each generation contains two types of leptons and two types of quarks. The two leptons may be classified into one with electric charge −1 (electron-like) and neutral (neutrino); the two quarks may be classified into one with charge − 1 ⁄ 3 (down-type) and one with charge + 2 ⁄ 3 (up-type).
The principle of pyrosequencing was first described in 1993 [1] by, Bertil Pettersson, Mathias Uhlen and Pål Nyren by combining the solid phase sequencing method [2] using streptavidin coated magnetic beads with recombinant DNA polymerase lacking 3´to 5´exonuclease activity (proof-reading) and luminescence detection using the firefly ...