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[3] [4] Antichlors are very useful in the textile industry because bleaching of compounds using chlorine is a standard practice. However, the use of sodium bisulfite in the decomposition of excess hypochlorite can lead to harmful byproducts when it comes into contact with water at the concentrations present for industrial use. [4]
Sodium bisulfate, also known as sodium hydrogen sulfate, [a] is the sodium salt of the bisulfate anion, with the molecular formula NaHSO 4.Sodium bisulfate is an acid salt formed by partial neutralization of sulfuric acid by an equivalent of sodium base, typically in the form of either sodium hydroxide (lye) or sodium chloride (table salt).
Sulfurous acid is commonly known to not exist in its free state, and due to this, it is stated in textbooks that it cannot be isolated in the water-free form. [4] However, the molecule has been detected in the gas phase in 1988 by the dissociative ionization of diethyl sulfite. [5]
Aluminum amalgam (Al/Hg) may be used for the chemoselective reduction of α-sulfonylated carbonyl groups. Carboxylic acid derivatives, acetals, thioacetals, amines, alcohols, and isolated double bonds are all inert to Al/Hg. Selective desulfonylation may be carried out on β-hydroxy sulfones without reductive elimination.
Of academic interest, SO 2 acts like a Lewis acid towards the alkyl ligand. [4] The pathway for the insertion of SO 2 into metal alkyl bond begins with attack of the alkyl nucleophile on the sulfur centre in SO 2. The "insertion" proceed the sulfur dioxide between the metal and the alkyl ligand leads to the O, O'-sulphinate.
Solutions of bisulfite are typically prepared by treatment of sulfur dioxide with aqueous base: [3]. SO 2 + OH − → HSO − 3. HSO − 3 is the conjugate base of sulfurous acid, (H 2 SO 3).
Sulfonyl groups can be written as having the general formula R−S(=O) 2 −R′, where there are two double bonds between the sulfur and oxygen. [1]: 53 [2]Sulfonyl groups can be reduced to the sulfide with diisobutylaluminium hydride (DIBALH).
Sodium sulfite (sodium sulphite) is the inorganic compound with the chemical formula Na 2 SO 3.A white, water-soluble solid, it is used commercially as an antioxidant and preservative.