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Olefin Conversion Technology, also called the Phillips Triolefin Process, is the industrial process that interconverts propylene with ethylene and 2-butenes. [1] The process is also called the ethylene to propylene (ETP) process. In ETP, ethylene is dimerized to 1-butene, which is isomerized to 2-butenes.
The Shell higher olefin process (SHOP) is a chemical process for the production of linear alpha olefins via ethylene oligomerization and olefin metathesis invented and exploited by Shell plc. [1] The olefin products are converted to fatty aldehydes and then to fatty alcohols , which are precursors to plasticizers and detergents .
In organic chemistry, olefin metathesis is an organic reaction that entails the redistribution of fragments of alkenes (olefins) by the scission and regeneration of carbon-carbon double bonds. [ 1 ] [ 2 ] Because of the relative simplicity of olefin metathesis, it often creates fewer undesired by-products and hazardous wastes than alternative ...
The main differences between each of them concerns the catalyst employed, design of the reactor and strategies to achieve higher conversion rates. [1] Olefins are useful precursors to myriad products. Steam cracking is the core technology that supports the largest scale chemical processes, i.e. ethylene and propylene. [2]
Grubbs catalysts are of interest for olefin metathesis. [ 25 ] [ 26 ] It is mainly applied to fine chemical synthesis. Large-scale commercial applications of olefin metathesis almost always employ heterogeneous catalysts or ill-defined systems based on ruthenium trichloride.
Gleason Corporation is a prominent machine tool builder based in Rochester, New York, US. [ 1 ] It has manufacturing plants in the US, Germany, Switzerland, China, Japan, and India as well as sales and service offices in all major industrial hubs globally.
This carbene collapses with loss of carbon dioxide to give the olefin. Proposed Mechanism of the Corey-Winter Olefination An alternative mechanism does not involve a free carbene intermediate, but rather involves attack of the carbanion by a second molecule of trimethylphosphite with concomitant cleavage of the sulfur-carbon bond.
Methanol can be converted to olefins using zeolite and SAPO-based heterogeneous catalysts. Depending on the catalyst pore size, this process can afford either C2 or C3 products, which are important monomers. [6] [7] Methanol to olefins technology is widely used in China in order to produce plastics from coal gasification.