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An isocyanide (also called isonitrile or carbylamine) is an organic compound with the functional group – N + ≡C −. It is the isomer of the related nitrile (–C≡N), hence the prefix is isocyano. [1] The organic fragment is connected to the isocyanide group through the nitrogen atom, not via the carbon. They are used as building blocks ...
Hydrogen isocyanide (HNC) is a linear triatomic molecule with C ∞v point group symmetry.It is a zwitterion and an isomer of hydrogen cyanide (HCN). [2] Both HNC and HCN have large, similar dipole moments, with μ HNC = 3.05 Debye and μ HCN = 2.98 Debye respectively. [3]
Linear triatomic molecules owe their geometry to their sp or sp 3 d hybridised central atoms. Well-known linear triatomic molecules include carbon dioxide (CO 2) and hydrogen cyanide (HCN). Xenon difluoride (XeF 2) is one of the rare examples of a linear triatomic molecule possessing non-bonded pairs of electrons on the central atom.
Because the CNC linkage is linear, the cone angle of these ligands is small, so it is easy to prepare polyisocyanide complexes. Many complexes of isocyanides show high coordination numbers, e.g. the eight-coordinate cation [Nb(CNBu−t) 6 I 2] +. [4] Very bulky isocyanide ligands are also known, e.g. C 6 H 3-2,6-Ar 2-NC (Ar =aryl). [5]
tert-Butyl isocyanide is an organic compound with the formula Me 3 CNC (Me = methyl, CH 3). It is an isocyanide , commonly called isonitrile or carbylamine, as defined by the functional group C≡N-R. tert -Butyl isocyanide, like most alkyl isocyanides, is a reactive colorless liquid with an extremely unpleasant odor.
Hydrogen cyanide is a linear molecule, with a triple bond between carbon and nitrogen.The tautomer of HCN is HNC, hydrogen isocyanide. [citation needed]HCN has a faint bitter almond-like odor that some people are unable to detect owing to a recessive genetic trait. [12]
In chemistry, linkage isomerism or ambidentate isomerism is a form of isomerism in which certain coordination compounds have the same composition but differ in their metal atom's connectivity to a ligand.
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