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Viscosity is a measure of a fluid's rate-dependent resistance to a change in shape or to movement of its neighboring portions relative to one another. [1] For liquids, it corresponds to the informal concept of thickness; for example, syrup has a higher viscosity than water. [2]
A simple and widespread empirical correlation for liquid viscosity is a two-parameter exponential: = / This equation was first proposed in 1913, and is commonly known as the Andrade equation (named after British physicist Edward Andrade). It accurately describes many liquids over a range of temperatures.
Consequently, if a liquid has dynamic viscosity of n centiPoise, and its density is not too different from that of water, then its kinematic viscosity is around n centiStokes. For gas, the dynamic viscosity is usually in the range of 10 to 20 microPascal-seconds, or 0.01 to 0.02 centiPoise. The density is usually on the order of 0.5 to 5 kg/m^3.
Relative viscosity (a synonym of "viscosity ratio") is the ratio of the viscosity of a solution to the viscosity of the solvent used (), =. The significance in Relative viscosity is that it can be analyzed the effect a polymer can have on a solution's viscosity such as increasing the solutions viscosity.
Physically, volume viscosity represents the irreversible resistance, over and above the reversible resistance caused by isentropic bulk modulus, to a compression or expansion of a fluid. [1] At the molecular level, it stems from the finite time required for energy injected in the system to be distributed among the rotational and vibrational ...
The derivation of the Navier–Stokes equations as well as their application and formulation for different families of fluids, is an important exercise in fluid dynamics with applications in mechanical engineering, physics, chemistry, heat transfer, and electrical engineering.
This functional relationship is described by a mathematical viscosity model called a constitutive equation which is usually far more complex than the defining equation of shear viscosity. One such complicating feature is the relation between the viscosity model for a pure fluid and the model for a fluid mixture which is called mixing rules.
Any equation that makes explicit one of these transport coefficient in the conservation variables is called an equation of state. [9] Apart from its dependence of pressure and temperature, the second viscosity coefficient also depends on the process, that is to say, the second viscosity coefficient is not just a material property.