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3-Methyl-2-butanol (IUPAC name, commonly called sec-isoamyl alcohol) is an organic chemical compound. It is used as a solvent and an intermediate in the manufacture of other chemicals. [ 3 ]
The reaction mechanism of the Mitsunobu reaction is fairly complex. The identity of intermediates and the roles they play has been the subject of debate. Initially, the triphenyl phosphine (2) makes a nucleophilic attack upon diethyl azodicarboxylate (1) producing a betaine intermediate 3, which deprotonates the carboxylic acid (4) to form the ion pair 5.
2-(1H-Indol-3-yl)ethanol Tryptophol: Primary 526-55-6 2-Methylbutan-1-ol: 2-Methyl-1-butanol (2M1B) Secondary 137-32-6 2-methylpropan-1-ol: 2-Methyl-1-propanol (2M1P), Isobutanol Primary 78-83-1 2-Methylbutan-2-ol: 2-Methyl-2-butanol (2M2B), tert-Amyl alcohol (TAA, tert-amylol) Tertiary 75-85-4 2-Methylpropan-2-ol
3-Methyl-2-butanol, an organic chemical compound used as a solvent and an intermediate Index of chemical compounds with the same name This set index article lists chemical compounds articles associated with the same name.
Neopentyl alcohol can be prepared from the hydroperoxide of diisobutylene. [3] It can also be prepared by the reduction of trimethylacetic acid with lithium aluminium hydride . Neopentyl alcohol was the first described in 1891 by L. Tissier, who prepared it by reduction of a mixture of trimethyl acetic acid and trimethylacetyl chloride with ...
When necessary, the position of the hydroxyl group is indicated by a number between the alkane name and the -ol: propan-1-ol for CH 3 CH 2 CH 2 OH, propan-2-ol for CH 3 CH(OH)CH 3. If a higher priority group is present (such as an aldehyde , ketone , or carboxylic acid ), then the prefix hydroxy- is used, [ 19 ] e.g., as in 1-hydroxy-2 ...
Proton transfer from the oxonium ion to a second molecule of the alcohol gives an activated complex; Protonation of one of the hydroxy groups of the activated complex gives a new oxonium ion. Loss of water from this oxonium ion and subsequent deprotonation gives the ester. A generic mechanism for an acid Fischer esterification is shown below.
[2] Through a variety of mechanisms, the removal of a hydride equivalent converts a primary or secondary alcohol to an aldehyde or ketone, respectively. The oxidation of primary alcohols to carboxylic acids normally proceeds via the corresponding aldehyde, which is transformed via an aldehyde hydrate (gem-diol, R-CH(OH) 2) by reaction with ...