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Structure of tetrachromic acid H 2 Cr 4 O 13 ·2H 2 O, one component of concentrated "chromic acid". The H-atom positions are calculated, not observed. Color code: red = O, white = H, blue = Cr. [7] Higher chromic acids with the formula H 2 Cr n O (3n+1) are probable components of concentrated solutions of chromic acid.
2 CrO 2− 4 + 2 H + ⇌ Cr 2 O 2− 7 + H 2 O. The predominance diagram shows that the position of the equilibrium depends on both pH and the analytical concentration of chromium. [notes 1] The chromate ion is the predominant species in alkaline solutions, but dichromate can become the predominant ion in acidic solutions.
Gel-like chromium(III) phosphate is prepared through the reduction of ammonium dichromate, (NH 4) 2 Cr 2 O 7, using ethanol, CH 3 COOH, and nitric acid, HNO 3.This process is done in the presence of ammonium dihydrogen phosphate and urea at an elevated temperature where tetradecyltrimethylammonium bromide (TTBr) is used as structure directing agent.
Chromium(III) hydroxide (Cr(OH) 3) is amphoteric, dissolving in acidic solutions to form [Cr(H 2 O) 6] 3+, and in basic solutions to form [Cr(OH) 6] 3−. It is dehydrated by heating to form the green chromium(III) oxide (Cr 2 O 3), a stable oxide with a crystal structure identical to that of corundum. [6]
Chromium(II) chloride describes inorganic compounds with the formula Cr Cl 2 (H 2 O) n.The anhydrous solid is white when pure, however commercial samples are often grey or green; it is hygroscopic and readily dissolves in water to give bright blue air-sensitive solutions of the tetrahydrate Cr(H 2 O) 4 Cl 2.
The formula of this compound can be written more descriptively as [Cr(H 2 O) 6] 2 (SO 4) 3 ·6H 2 O. Six of the eighteen water molecules in this formula unit are water of crystallization. Hydrated chromium(III) sulfate, Cr 2 (SO 4) 3 ·15(H 2 O), (CAS #10031-37-5) is a green solid that also readily dissolves in water. It is obtained by heating ...
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Chromium(II) sulfate is an inorganic compound with the chemical formula Cr S O 4. It often comes as hydrates CrSO 4 ·nH 2 O. Several hydrated salts are known. The pentahydrate CrSO 4 ·5H 2 O is a blue solid that dissolves readily in water. Solutions of chromium(II) are easily oxidized by air to Cr(III) species.