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Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials.
Recording optical rotation with a polarimeter: The plane of polarisation of plane polarised light (4) rotates (6) as it passes through an optically active sample (5). This angle is determined with a rotatable polarizing filter (7). In chemistry, specific rotation ([α]) is a property of a chiral chemical compound.
In all materials the rotation varies with wavelength. The variation is caused by two quite different phenomena. The first accounts in most cases for the majority of the variation in rotation and should not strictly be termed rotatory dispersion. It depends on the fact that optical activity is actually circular birefringence.
A polarimeter [1] is a scientific instrument used to measure optical rotation: the angle of rotation caused by passing linearly polarized light through an optically active substance. [ 2 ] Some chemical substances are optically active, and linearly polarized (uni-directional) light will rotate either to the left (counter-clockwise) or right ...
A half-wave plate rotates polarization by 90° A polarization rotator is an optical device that rotates the polarization axis of a linearly polarized light beam by an angle of choice. Such devices can be based on the Faraday effect, on birefringence, or on total internal reflection. [1]
Michael Faraday holding a piece of glass of the type he used to demonstrate the effect of magnetism on polarization of light, c. 1857.. By 1845, it was known through the work of Augustin-Jean Fresnel, Étienne-Louis Malus, and others that different materials are able to modify the direction of polarization of light when appropriately oriented, [4] making polarized light a very powerful tool to ...
Mueller calculus is a matrix method for manipulating Stokes vectors, which represent the polarization of light. It was developed in 1943 by Hans Mueller. In this technique, the effect of a particular optical element is represented by a Mueller matrix—a 4×4 matrix that is an overlapping generalization of the Jones matrix.
The Stokes I, Q, U and V parameters. The Stokes parameters are a set of values that describe the polarization state of electromagnetic radiation.They were defined by George Gabriel Stokes in 1851, [1] [2] as a mathematically convenient alternative to the more common description of incoherent or partially polarized radiation in terms of its total intensity (I), (fractional) degree of ...