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[18] [19] This led to the discovery by Yasumitsu Aoki (Nemoto & Co.) of materials with luminance approximately 10 times greater than zinc sulfide and phosphorescence approximately 10 times longer. [20] [21] This has relegated most zinc sulfide based products to the novelty category. Strontium aluminate based pigments are now used in exit signs ...
Blue: Combination of zinc sulfide with few ppm of silver, the ZnS:Ag, when excited by electrons, provides strong blue glow with maximum at 450 nm, with short afterglow with 200 nanosecond duration. It is known as the P22B phosphor. This material, zinc sulfide silver, is still one of the most efficient phosphors in cathode-ray tubes. It is used ...
Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite . Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment.
Silver, added to zinc sulfide to produce a phosphor/scintillator used in radium dials, spinthariscopes, and as a common blue phosphor in color CRTs, and to zinc sulfide-cadmium sulfide used as a phosphor in black-and-white CRTs (where the ZnS/(Zn,Cd)S ratio determines the blue/yellow balance of the resulting white); short afterglow
Various preparations of the phosphor compound can be used to produce different colors of light. For example, doping zinc sulfide phosphor with different metals can change the emission wavelength. [4] Some of the colors that have been manufactured in addition to the common phosphors are green, red, blue, yellow, purple, orange, and white.
Jablonski diagram including vibrational levels for absorbance, non-radiative decay, and fluorescence. When a molecule absorbs a photon, the photon energy is converted and increases the molecule's internal energy level. Likewise, when an excited molecule releases energy, it can do so in the form of a photon.
A fine structure corresponding to molecular vibrational modes is associated with each of those electron levels. The energy spacing between electron levels is ≈1 eV; the spacing between the vibrational levels is about 1/10 of that for electron levels. [36] An incoming particle can excite either an electron level or a vibrational level.
Strontium aluminates are now the longest lasting and brightest phosphorescent material commercially available. For many phosphorescence-based purposes, strontium aluminate is a superior phosphor to its predecessor, copper-activated zinc sulfide, being about 10 times brighter and 10 times longer glowing.