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Arsenic trioxide powder.. Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table.The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds.
Arsenic and its compounds, especially the trioxide, are used in the production of pesticides, treated wood products, herbicides, and insecticides. These applications are declining with the increasing recognition of the toxicity of arsenic and its compounds. [15] Arsenic has been known since ancient times to be poisonous to humans. [16]
Arsenic compounds have been known for at least 5000 years, and the ancient Greek Theophrastus recognized the arsenic minerals called realgar and orpiment. Elemental arsenic was discovered in the 13th century by Albertus Magnus. [14] Antimony was well known to the ancients. A 5000-year-old vase made of nearly pure antimony exists in the Louvre.
For example, the mold Scopulariopsis brevicaulis produces significant amounts of trimethylarsine if inorganic arsenic is present. [10] Biomethylation of arsenic compounds starts with the formation of methanearsonates. Thus, trivalent inorganic arsenic compounds are methylated to give methanearsonate. S-adenosylmethionine is the methyl donor.
Arsine (IUPAC name: arsane) is an inorganic compound with the formula As H 3. This flammable, pyrophoric, and highly toxic pnictogen hydride gas is one of the simplest compounds of arsenic. [4] Despite its lethality, it finds some applications in the semiconductor industry and for the synthesis of organoarsenic compounds.
These compounds are mainly of academic interest. For example, "sodium arsenide" is a structural motif adopted by many compounds with the A 3 B stoichiometry. Indicative of their salt-like properties, hydrolysis of alkali metal arsenides gives arsine: Na 3 As + 3 H 2 O → AsH 3 + 3 NaOH Nickel arsenide is a common impurity in ores of nickel.
For chemical compounds containing arsenic. For an alternative listing please see inorganic_compounds_by_element#Arsenic . Wikimedia Commons has media related to Arsenic compounds .
Arsenic pentoxide, As 2 O 5 Index of chemical compounds with the same name This set index article lists chemical compounds articles associated with the same name.