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Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
The Br–Br distance is 227 pm (close to the gaseous Br–Br distance of 228 pm) and the Br···Br distance between molecules is 331 pm within a layer and 399 pm between layers (compare the van der Waals radius of bromine, 195 pm). This structure means that bromine is a very poor conductor of electricity, with a conductivity of around 5 × 10 ...
The energy required to remove one or more electrons to make a cation is a sum of successive ionization energies; for example, the energy needed to form Mg 2+ is the ionization energy required to remove the first electron from Mg, plus the ionization energy required to remove the second electron from Mg +. Electron affinity is defined as the ...
The electron affinity (usually given by the symbol in solid state physics) gives the energy difference between the lower edge of the conduction band and the vacuum level of the semiconductor. The band gap (usually given the symbol E g {\displaystyle E_{\rm {g}}} ) gives the energy difference between the lower edge of the conduction band and the ...
One can test for a bromide ion by adding an oxidizer. One method uses dilute HNO 3. Balard and Löwig's method can be used to extract bromine from seawater and certain brines. For samples testing for sufficient bromide concentration, addition of chlorine produces bromine (Br 2): [7] Cl 2 + 2 Br − → 2 Cl − + Br 2
The bromide ion acquires a positive formal charge. At this moment the halogen ion is called a "bromonium ion" or "chloronium ion", respectively. When the first bromine atom attacks the carbon–carbon π-bond, it leaves behind one of its electrons with the other bromine that it was bonded to in Br 2.
For example, the electron binding energy for removing a 3p 3/2 electron from the chloride ion is the minimum amount of energy required to remove an electron from the chlorine atom when it has a charge of −1. In this particular example, the electron binding energy has the same magnitude as the electron affinity for the