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The ideal gas law is used for these calculations. Often, but not always, the standard temperature and pressure (STP) are taken as 0 °C and 1 bar and used as the conditions for gas stoichiometric calculations. Gas stoichiometry calculations solve for the unknown volume or mass of a gaseous product or reactant.
The energy required to vaporize the water is therefore lost. LHV calculations assume that the water component of a combustion process is in vapor state at the end of combustion, as opposed to the higher heating value (HHV) (a.k.a. gross calorific value or gross CV) which assumes that all of the water in a combustion process is in a liquid state ...
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure.
Hess's law states that the change of enthalpy in a chemical reaction is the same regardless of whether the reaction takes place in one step or several steps, provided the initial and final states of the reactants and products are the same. Enthalpy is an extensive property, meaning that its value is proportional to the system size. [4]
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
A ratio of 1 corresponds to the stoichiometric ratio Constant volume flame temperature of a number of fuels, with air. If we make the assumption that combustion goes to completion (i.e. forming only CO 2 and H 2 O), we can calculate the adiabatic flame temperature by hand either at stoichiometric conditions or lean of stoichiometry (excess air ...
The stoichiometry of a chemical reaction is based on chemical formulas and equations that provide the quantitative relation between the number of moles of various products and reactants, including yields. [8] Stoichiometric equations are used to determine the limiting reagent or reactant—the reactant that is completely consumed in a reaction ...