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Phosphorus has a melting point of 44 °C and a boiling point of 280 °C. Arsenic is one of only two elements to sublimate at standard pressure; it does this at 603 °C. Antimony's melting point is 631 °C and its boiling point is 1587 °C. Bismuth's melting point is 271 °C and its boiling point is 1564 °C. [13]
White phosphorus, yellow phosphorus or simply tetraphosphorus (P 4) exists as molecules of four phosphorus atoms in a tetrahedral structure, joined by six phosphorus—phosphorus single bonds. [1] The free P 4 molecule in the gas phase has a P-P bond length of r g = 2.1994(3) Å as was determined by gas electron diffraction . [ 2 ]
Phosphorus is an essential plant nutrient (the most often limiting nutrient, after nitrogen), [110] and the bulk of all phosphorus production is in concentrated phosphoric acids for agriculture fertilisers, containing as much as 70% to 75% P 2 O 5. That led to large increase in phosphate (PO 4 3−) production in the second half of the 20th ...
When it is converted to the covalent red phosphorus, the density goes to 2.2–2.4 g/cm 3 and melting point to 590 °C, and when white phosphorus is transformed into the (also covalent) black phosphorus, the density becomes 2.69–3.8 g/cm 3 and melting temperature ~200 °C. Both red and black phosphorus forms are significantly harder than ...
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
Boca Raton, Florida, 2003; Section 6, Fluid Properties; Critical Constants. Also agrees with Celsius values from Section 4: Properties of the Elements and Inorganic Compounds, Melting, Boiling, Triple, and Critical Point Temperatures of the Elements Estimated accuracy for Tc and Pc is indicated by the number of digits.
White phosphorus, yellow phosphorus, or simply tetraphosphorus (P 4) is an allotrope of phosphorus. It is a translucent waxy solid that quickly yellows in light (due to its photochemical conversion into red phosphorus ), [ 2 ] and impure white phosphorus is for this reason called yellow phosphorus.
The Gmelin rare earths handbook lists 1522 °C and 1550 °C as two melting points given in the literature, the most recent reference [Handbook on the chemistry and physics of rare earths, vol.12 (1989)] is given with 1529 °C.