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Solid-phase electrical conductivity: Variable, [6] depending on the nature of the bonding: network solids in which all electrons are used for sigma bonds (e.g. diamond, quartz) are poor conductors, as there are no delocalized electrons. However, network solids with delocalized pi bonds (e.g. graphite) or dopants can exhibit metal-like conductivity.
A network covalent solid consists of atoms held together by a network of covalent bonds (pairs of electrons shared between atoms of similar electronegativity), and hence can be regarded as a single, large molecule. The classic example is diamond; other examples include silicon, [3] quartz and graphite.
In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.
Solid-state physics is the study of rigid matter, or solids, through methods such as solid-state chemistry, quantum mechanics, crystallography, electromagnetism, and metallurgy. It is the largest branch of condensed matter physics. Solid-state physics studies how the large-scale properties of solid materials result from their atomic-scale ...
Inelastic characteristics must be considered as well, and shear modulus might even provide a better correlation with hardness than bulk modulus. Covalent materials generally have high bond-bending force constants and high shear moduli and are more likely to give superhard structures than, for example, ionic solids. [10] [11]
The bonding in boron has been described as being characteristic of behaviour intermediate between metals and nonmetallic covalent network solids (such as diamond). [255] The energy required to transform B, C, N, Si, and P from nonmetallic to metallic states has been estimated as 30, 100, 240, 33, and 50 kJ/mol, respectively.
(Bottom) Graphite crystal structure, depicting an atomic spacing of 0.142 nm. Atomic spacing refers to the distance between the nuclei of atoms in a material. This space is extremely large compared to the size of the atomic nucleus , and is related to the chemical bonds which bind atoms together. [ 1 ]
As a metalloid the chemistry of silicon is largely covalent in nature, noting it can form alloys with metals such as iron and copper. The common oxide of silicon (SiO 2) is weakly acidic. Germanium. Germanium is a shiny, mostly unreactive grey-white solid with a density of 5.323 g/cm 3 (about two-thirds that of iron), and is hard (MH 6.0) and ...